Overview of Cathodic Protection

Cathodic Protection (CP) is one of the most effective methods for preventing most types of corrosion on a metal surface. In some cases, CP can even stop corrosion damage from occurring. Metals, especially ferrous metals, corrode in the presence of oxygen, water, and other impurities such as sulfur. Without CP, metals act as the anode and easily lose their electrons and thus, the metal becomes oxidized and corroded. CP simply supplies the metal with electrons from an external source, making it a cathode.

Basic Terminology

Oxidation — Loss of electrons

Reduction — Gain of electrons

Anode — Where oxidation reactions take place

Cathode — Where reduction reactions take place

The following are two helpful mnemonics to remember how electrons are transferred in oxidation-reduction (redox) reactions.

1. OILRIG — Oxidation is Loss, Reduction is Gain
2. AnOx RedCat — Anode is for Oxidation, Reduction at the Cathode

Types of Cathodic Protection

1. Galvanic Cathodic Protection

Galvanic cathodic protection involves protecting a metal surface of a piece of equipment using another metal that is more reactive. The latter metal, usually called the galvanic or sacrificial anode, has a less negative electrochemical potential compared to the metal component being protected. Therefore, the sacrificial anode undergoes oxidation rather than the operating equipment. This technique is illustrated in Figure 1 below for an offshore platform with a steel pipe submerged into seawater. The sacrificial anode is an aluminum anode in this example.

Sometimes, steels are galvanized rather than connected to galvanic anodes. Galvanized steels are steels that are coated with a protective zinc layer. The zinc layer acts to cathodically protect steel against corrosion in most underground and marine environments.

2. Impressed Current Cathodic Protection (ICCP)

ICCP is a more economical method of CP when underground pipelines are long or offshore equipment is too large to protect via one or few galvanic anodes. In ICCP, electrons are supplied to the cathodic structure using an external DC power source (also called a rectifier). The steel component is connected to the negative terminal of the power source and the impressed current anodes are connected to the positive terminal of the power source. For simplicity, Figure 2 shows one cathode and one anode connected by a rectifier. In application, multiple anodes are connected to the positive terminal of the power source.

Industry Applications of Cathodic Protection

Cathodic protection is routinely used to protect equipment operating in aggressive environments. The two most common applications of CP are for buried pipeline systems and vessels as well as offshore platforms. CP is not used to protect equipment in atmospheric conditions or protect components internally.

CP Challenges

Once installed, CP should be monitored and maintained. Furthermore, inadequate CP designs may not maximize the amount of current reaching the protected item. CP designs should consider the environmental conditions and the component to be protected against corrosion. Another critical factor to monitor is stray currents that may interfere with the system. These interfering currents could be due to the environment or neighboring components (especially if new equipment is commissioned). Additionally, the anodes and rectifiers must be maintained in order for CP to be effective and reliable.

Relevant Standards and Regulations

• 49 CFR 192.451 - Requirements for Corrosion Control - Transportation of Natural and Other Gas by Pipelines: US Minimum Federal Safety Standards
• 49 CFR 192.551 - Requirements for Corrosion Control - Transportation of Hazardous Liquids by Pipelines: US Minimum Federal Safety Standards
• API RP 651 - Cathodic Protection of Aboveground Petroleum Storage Tanks

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Related Topics

Coatings Condition Monitoring Locations (CMLs) Corrosion Control Documents (CCDs) Damage Mechanisms Flue Gas Dew Point Corrosion Green Rot Pitting Corrosion Positive Material Identification (PMI)